Nitriding effects of ammonia flames on iron-based metal walls

Wang, Daoyuan, Lee, Minhyeok ORCID: https://orcid.org/0000-0002-2095-8705 and Suzuki, Yuji ORCID: https://orcid.org/0000-0002-6844-1449 2023. Nitriding effects of ammonia flames on iron-based metal walls. Journal of Ammonia Energy 1 (1) 10.18573/jae.8

Preview

PDF - Published Version Available under License Creative Commons Attribution Non-commercial No Derivatives. Download (1MB) | Preview

Abstract

Effects of NH3/O2/N2 premixed flame/mixture on iron-based metal walls have been investigated experimentally. A premixed NH3/O2/N2 flame or mixture formed by a quartz tube burner impinged on the disc-shaped metal test plate, of which the temperature was kept at 550 oC by an infrared lamp heater. As materials for the test plate, SACM645, SUS304 and SUS310S, which are widely used as industrial steels, were examined. After being exposed to either the NH3/O2/N2 flame or mixture for 5 hours, the surface hardness was measured by using a nano indenter. Distributions of nitrogen atom diffused into the metal wall were measured by means of the Electron Probe Micro Analyzer (EPMA) and Secondary Ion Mass Spectrometry (SIMS). In addition, spatial distributions of the NH3 concentration in the NH3/O2/N2 flame and mixture were measured by employing a two-photon absorption laser-induced fluorescence (TALIF) technique. It was found that the surface hardness of the test plates increased significantly after being exposed to the NH3/O2/N2 flame/mixture. The distributions of surface hardness and nitrogen atom concentration show that nitriding occurred by the present NH3/O2/N2 flame/mixture with the equivalent level of the conventional gas nitriding method. Moreover, it is also found that NH3 concentration in the vicinity of the wall plays an important role in the surface hardness increase, and a wider distribution of NH3 can result in a broader surface hardness distribution.

Item Type:	Article
Date Type:	Publication
Status:	Published
Publisher:	Cardiff University Press
ISSN:	2752-7735
Funders:	JSPS KAKENHI, NEDO, JST SICORP EIG CONCERT-Japan, ARIM, Paloma Environmental Technology Development Foundation
Date of First Compliant Deposit:	10 November 2023
Date of Acceptance:	31 March 2023
Last Modified:	10 Nov 2023 15:44
URI:	https://orca.cardiff.ac.uk/id/eprint/163815

Actions (repository staff only)

Edit Item