Achieving molecular-level selective detection of volatile organic compounds through a strong coupling effect of ultrathin nanosheets and Au nanoparticles

Ou, Yucheng, Zhai, Liangyu, Zhu, Gangqiang, Zhang, Weibin, Huang, Xiaoyang, Akdim, Ouardia, Zhu, Lujun, Nie, Junli, Rao, Fei, Huang, Yu, Shi, Xianjin, Gao, Jianzhi, Lu, Hongbin and Hojamberdiev, Mirabbos 2023. Achieving molecular-level selective detection of volatile organic compounds through a strong coupling effect of ultrathin nanosheets and Au nanoparticles. ACS Sensors 9 (1) , 139–148. 10.1021/acssensors.3c01777

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Abstract

The high density of surface active sites, high efficiency of interfacial carrier transport, and molecular diffusion path determine the efficiency of the electrochemical sensors. The ultrathin structures have atomic-level thickness, carrier migration and heat diffusion are limited in the two-dimensional plane, resulting in excellent conductivity and high carrier concentration. A one-step chemical method is applied to synthesize defect-rich Au-SnO2 in an ultrathin nanosheet form (thickness of 2–3 nm). The strong interaction between Au and SnO2 via the Au–O–Sn bonding and the catalytic effect of Au can prolong the service life via decreasing the optimal operating temperature (55 °C) and promote the Au-SnO2 sensor to exclusively detect formaldehyde at the ppb level (300 ppb). The experimental findings along with theoretical study reveal that Au nanoparticles have a different effect on the competitive adsorption and chemical reaction over the surface of the Au–SnO2 with formaldehyde and other interfering VOC gases, such as methanol, ethanol, and acetone. This study provides mechanistic insights into the correlation between operating temperature and the performance of the Au–SnO2 chemiresistive sensor. This work allows the development of highly efficient and stable electrochemical sensors to detect VOC gases at room temperature in the future.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	American Chemical Society
ISSN:	2379-3694
Date of First Compliant Deposit:	21 February 2024
Date of Acceptance:	30 November 2023
Last Modified:	14 Dec 2024 02:45
URI:	https://orca.cardiff.ac.uk/id/eprint/166430

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