Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment

Aldridge, Simon, Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001, Al-Fawaz, Amal, Jones, Kevin M., Horton, Peter N., Hursthouse, Michael B., Harrington, Ross W. and Clegg, William 2006. Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. Chemical Communications (24) , pp. 2578-2580. 10.1039/B604141H

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Abstract

The reaction of (η5-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C–H insertion) to the Cp ring, thereby generating the zwitterion [η5-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of Acceptance:	21 April 2006
Last Modified:	11 Jul 2024 15:15
URI:	https://orca.cardiff.ac.uk/id/eprint/170279

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