Structures of the metallated trihalogallate and indate ions [(η5-C5Me5)Fe(CO)2InI 3]- and [(η5-C5H 5)Fe(CO)2GaI2Br-]

Aldridge, Simon, Kays, Deborah L., Bunn, Natalie R., Coombs, Natalie D. and Ooi, Li-ling 2005. Structures of the metallated trihalogallate and indate ions [(η5-C5Me5)Fe(CO)2InI 3]- and [(η5-C5H 5)Fe(CO)2GaI2Br-]. Main Group Metal Chemistry 28 (4) , pp. 201-206. 10.1515/MGMC.2005.28.4.201

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Abstract

The metallated trihalogallate and indate ions [^5-C5R5)Fe(CO)2E(X)2XT (1: R = Me, Ε = In, X = X' = I; 2: R = Η, Ε = Ga, X = I, X' = Br) isolated as the [^5-C5Me5)Fe^6-C6H5Me)]+ and [Et3NH]+ salts, respectively, each features a staggered conformation about the Fe-E bond [Z centroid-Fe-E-X' = 178.9(3) (for 1) and 176.6(10)° (for 2)]. 1 represents the first crystallographically characterized half-sandwich iron complex containing a pendant trihaloindate fragment.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Freund Publishing House / Walter de Gruyter
ISSN:	0792-1241
Last Modified:	10 Jul 2024 11:00
URI:	https://orca.cardiff.ac.uk/id/eprint/170280

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