Synthesis and characterisation of complexes of the 2,6-diphenoxyphenyl ligand

Blake, Alexander J., Gower, Alexandra L., Lewis, William, Moxey, Graeme J., Reade, Thomas J. and Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001 2011. Synthesis and characterisation of complexes of the 2,6-diphenoxyphenyl ligand. Journal of Organometallic Chemistry 696 (9) , pp. 1787-1791. 10.1016/j.jorganchem.2010.12.023

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Abstract

The use of the 2,6-diphenoxyphenyl ligand has facilitated the stabilisation of lithium, silane and stannane complexes. The ortho-metallation reaction between 1,3-(PhO)2C6H4 and nBuLi yields 2,6-(PhO)2C6H3Li (1); the crystallographically characterised dimer [2,6-(PhO)2C6H3Li(OEt2)]2 ([1.Et2O]2) can be obtained by the crystallisation of 1 from diethyl ether. The reaction between 1 and Me3ECl gives rise to the structurally authenticated complexes 2,6-(PhO)2C6H3EMe3 [E = Si, 2; E = Sn, 3].

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Elsevier
ISSN:	0022-328X
Date of Acceptance:	20 December 2010
Last Modified:	10 Jul 2024 09:16
URI:	https://orca.cardiff.ac.uk/id/eprint/170285

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