Recent developments in transition metal diaryl chemistry

Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001 2011. Recent developments in transition metal diaryl chemistry. Dalton Transactions 40 (4) , pp. 769-778. 10.1039/C0DT01247E

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Abstract

This Perspective discusses the synthesis and reactivity of low-coordinate transition metal diaryl complexes. The development of sterically demanding ligands, in particular m-terphenyls is facilitating the isolation of complexes featuring two-coordinate open-shell transition metal centres. These coordinatively unsaturated complexes are now being investigated for their reaction chemistry, which is not only contributing to the elucidation of the structure and bonding within these systems but is also leading to the formation of novel compounds.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Date of Acceptance:	8 November 2010
Last Modified:	10 Jul 2024 16:00
URI:	https://orca.cardiff.ac.uk/id/eprint/170310

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