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Monomeric, two-coordinate Mn, Fe and Co(II) complexes featuring 2,6-(2,4,6-trimethylphenyl)phenyl ligands

Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001 and Cowley, Andrew R. 2007. Monomeric, two-coordinate Mn, Fe and Co(II) complexes featuring 2,6-(2,4,6-trimethylphenyl)phenyl ligands. Chemical Communications (10) , pp. 1053-1055. 10.1039/B616584B

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Abstract

The synthesis and characterization of the monomeric, two-coordinate transition-metal complexes (2,6-Mes2C6H3)2M (Mes = mesityl, 2,4,6-Me3C6H2, M = Mn, Fe, Co) are reported; (2,6-Mes2C6H3)2Co is the first structurally authenticated two-coordinate, homoleptic cobalt(II) complex featuring σ-bonded aryl ligands.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of Acceptance: 15 January 2007
Last Modified: 11 Jul 2024 15:00
URI: https://orca.cardiff.ac.uk/id/eprint/170313

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