Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer

Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001, Day, Joanna K., Aldridge, Simon, Harrington, Ross W. and Clegg, William 2006. Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer. Angewandte Chemie - International Edition 45 (21) , pp. 3513-3516. 10.1002/anie.200600714

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Abstract

It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein–Ponndorf β-hydride transfer from the aminoborylene ligand to the coordinated ketone generates 2 (see structure), the first example of an imine-donor-stabilized borylene complex, and the first cationic alkoxyborylene system.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1433-7851
Last Modified:	12 Jul 2024 12:01
URI:	https://orca.cardiff.ac.uk/id/eprint/170314

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