Cationic terminal borylene complexes: a synthetic and mechanistic investigation of m=b metathesis chemistry

Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001, Day, Joanna K., Ooi, Li-Ling and Aldridge, Simon 2005. Cationic terminal borylene complexes: a synthetic and mechanistic investigation of m=b metathesis chemistry. Angewandte Chemie - International Edition 44 (45) , pp. 7457-7460. 10.1002/anie.200502343

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Abstract

Halide abstraction chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3PS or Ph3AsO to form 3 and 4. In the case of the corresponding reaction with Ph3PO, the intermediate 2 can be isolated, which provides evidence for a two-step addition/substitution mechanism for the overall metathesis reaction.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1433-7851
Last Modified:	12 Jul 2024 13:15
URI:	https://orca.cardiff.ac.uk/id/eprint/170315

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