Dehydrogenation of dimethylamine-borane mediated by group 1 pincer complexes

Nolla-Saltiel, Roberto, Geer, Ana M., Lewis, William, Blake, Alexander J. and Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001 2018. Dehydrogenation of dimethylamine-borane mediated by group 1 pincer complexes. Chemical Communications 54 (15) , pp. 1825-1828. 10.1039/C7CC08385H

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Abstract

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of Acceptance:	4 January 2018
Last Modified:	12 Jul 2024 10:00
URI:	https://orca.cardiff.ac.uk/id/eprint/170324

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