Bunn, Natalie R., Aldridge, Simon, Coombs, Deborah L.  ORCID: https://orcid.org/0000-0002-4616-6001, Rossin, Andrea, Willock, David J.  ORCID: https://orcid.org/0000-0002-8893-1090, Jones, Cameron and Ooi, Li-ling
      2004.
      
      Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.
      Chemical Communications
      
      
        (15)
      
      , pp. 1732-1733.
      
      10.1039/B405943C
    
  
  
       
       
     
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      Official URL: http://dx.doi.org/10.1039/B405943C
    
  
  
    Abstract
This communication reports the synthesis and characterization of the cationic iron complex [{(η5-C5Me5)Fe(CO)2}2Ga]+[BArf4]− [Arf = C6H3(CF3)2-3,5] containing a symmetrically bridging two-coordinate gallium atom and a delocalised Fe–Ga–Fe π system incorporating partial Fe–Ga multiple bond character.
| Item Type: | Article | 
|---|---|
| Date Type: | Publication | 
| Status: | Published | 
| Schools: | Schools > Chemistry | 
| Publisher: | Royal Society of Chemistry | 
| ISSN: | 1359-7345 | 
| Last Modified: | 12 Jul 2024 14:15 | 
| URI: | https://orca.cardiff.ac.uk/id/eprint/170536 | 
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