Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre

Bunn, Natalie R., Aldridge, Simon, Coombs, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001, Rossin, Andrea, Willock, David J. ORCID: https://orcid.org/0000-0002-8893-1090, Jones, Cameron and Ooi, Li-ling 2004. Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre. Chemical Communications (15) , pp. 1732-1733. 10.1039/B405943C

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Abstract

This communication reports the synthesis and characterization of the cationic iron complex [{(η5-C5Me5)Fe(CO)2}2Ga]+[BArf4]− [Arf = C6H3(CF3)2-3,5] containing a symmetrically bridging two-coordinate gallium atom and a delocalised Fe–Ga–Fe π system incorporating partial Fe–Ga multiple bond character.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Last Modified:	12 Jul 2024 14:15
URI:	https://orca.cardiff.ac.uk/id/eprint/170536

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