Time scales and mechanisms of uranium uptake in altered ocean crust; observations from the ∼15 million year-old site 1256 in the eastern equatorial Pacific

Andersen, Morten ORCID: https://orcid.org/0000-0002-3130-9794, Rodney, Joel, Freymuth, Heye, Vils, Flurin, Harris, Michelle, Cooper, Kari, Teagle, Damon A. H. and Elliott, Tim 2024. Time scales and mechanisms of uranium uptake in altered ocean crust; observations from the ∼15 million year-old site 1256 in the eastern equatorial Pacific. Geochimica et Cosmochimica Acta 10.1016/j.gca.2024.07.028

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Abstract

The alteration of ocean crust through hydrothermal seawater circulation facilitates chemical exchange between Earth’s surface and interior. Hydrothermal alteration leads to uranium (U) removal from seawater and net U uptake by the ocean crust, particularly during low temperature alteration that occurs on the vast ocean ridge flanks away from the spreading axes. Determining the timescales of U uptake and its associated 238U/235U signature has important implications for understanding U exchange processes during subduction and recycling into the mantle. Here we study the U systematics of ∼15 million year-old ocean crust drilled at Site 1256 on the eastern flank of the East Pacific Rise. Analysis of cores from the upper ∼1300 m of intact ocean crust at this site, reveal large variability in U concentrations and 238U/235U ratios. Many of the samples from the upper ∼600 m of extrusive lavas have elevated U concentrations and 238U/235U ratios lower than seawater, consistent with mechanisms of U uptake under relatively oxidised conditions. Samples from the underlying sheeted dikes and gabbros show evidence for hydrothermal U mobilisation, but negligible net U uptake. In contrast, in the transition zone between the extrusive lavas and the sheeted dikes, samples revealed large U enrichments and high 238U/235U ratios above seawater. This is consistent with uptake of the reduced U+4 species under relatively reducing conditions from seawater-derived hydrothermal fluids. In addition, large secular disequilibrium in 234U/238U ratios from samples in the lava-dike transition and upper sheeted dikes give evidence for U mobility within the last ∼1.5 million years, likely driven by deep channelled flow of seawater-derived hydrothermal fluids combined with preferential leaching of 234U from the rock matrix. Both the total estimated U uptake and mean 238U/235U at Site 1256 is lower than similar estimates from significantly older (>100 million years) altered ocean crusts at drill Sites 801 and 417/418. This shows the variable total U uptake and 238U/235U ratio in altered ocean crust over time, which needs to be taken into consideration when estimating global U budgets.

Item Type:	Article
Date Type:	Published Online
Status:	In Press
Schools:	Earth and Environmental Sciences
Publisher:	Elsevier
ISSN:	1872-9533
Date of First Compliant Deposit:	26 July 2024
Date of Acceptance:	22 July 2024
Last Modified:	15 Aug 2024 15:45
URI:	https://orca.cardiff.ac.uk/id/eprint/170950

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