Exploring 1T/2H MoS2 nano coral structured active electrodes for enhanced pseudocapacitive supercapacitors: a rigorous evaluation and characterization study

Kavipriyah, M.N., Subburaj, Surender and Subramanian, Balakumar 2024. Exploring 1T/2H MoS2 nano coral structured active electrodes for enhanced pseudocapacitive supercapacitors: a rigorous evaluation and characterization study. Electrochimica Acta 505 , 144920. 10.1016/j.electacta.2024.144920 Item availability restricted.

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Abstract

This article optimizes the synthesis parameters of nano coral structured (NC-S) molybdenum disulfide (MoS2) using hydrothermal method and enhances its physiochemical properties for high-performance supercapacitors (SC). This nano coral architecture of transition metal dichalcogenides has garnered significant attention for efficient pseudocapacitive charge storage in SC. Herein, this work demonstrates the fabrication of dual phase MoS2 by tailoring the reaction time of the NC-S, furthermore this effect has been explained with the help of several analytical techniques. The synthesized 1T/2H MoS2 NC-S phase was affirmed by powder X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy studies. The field emission scanning electron microscope and transmission electron microscope images unveiled nano corals like morphology with numerous active sites. Impressively, the as prepared 24, 36 and 48 h MoS2 NC-S entrenched as working electrode endows the achievement with a greater specific capacitance of about 761.82, 1550.86 and 1036.28 F/g at 1 A/g of current density manifests an outstanding rate capability of 94.5, 96.5 and 95.3% capacitive retention even after 1000 cycles. Among them, the 36 h (A-36) synthesized NC-S MoS2 possess high specific energy (43.61 Wh /kg) and power (225.50 W/kg) for this application. Additionally, it demonstrates a commendable capacitive retention of 97% for the two-cell asymmetric setup, even after 5000 cycles at 10 A/g of current density. This inventive configuration of a two-cell device is employed using a Swagelok setup, where the 1T/2H phase MoS2 NC-S//AC exhibit outstanding storage stability and sustained up to 180 sec. The promising results validate that this material can significantly enhance performance in energy storage applications.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Engineering
Additional Information:	License information from Publisher: LICENSE 1: Title: This article is under embargo with an end date yet to be finalised.
Publisher:	Elsevier
ISSN:	0013-4686
Date of First Compliant Deposit:	20 August 2024
Date of Acceptance:	16 August 2024
Last Modified:	07 Nov 2024 23:15
URI:	https://orca.cardiff.ac.uk/id/eprint/171494

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