Abdul Nasir, Jamal, Beale, Andrew M. and Catlow, C. Richard A. ![]() ![]() |
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Abstract
Transition-metal-containing zeolites have wide-ranging applications in several catalytic processes including the selective catalytic reduction (SCR) of NOx species. To understand how transition metal ions (TMIs) can effect NOx reduction chemistry, both structural and mechanistic aspects at the atomic level are needed. In this review, we discuss the coordination chemistry of TMIs and their mobility within the zeolite framework, the reactivity of active sites, and the mechanisms and intermediates in the NH3-SCR reaction. We emphasise the key relationship between TMI coordination and structure and mechanism and discuss approaches to enhancing catalytic activity via structural modifications.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Cardiff Catalysis Institute (CCI) Chemistry |
Additional Information: | License information from Publisher: LICENSE 1: URL: https://creativecommons.org/licenses/by/3.0/, Start Date: 2024-10-23 |
Publisher: | Royal Society of Chemistry |
ISSN: | 0306-0012 |
Date of First Compliant Deposit: | 24 October 2024 |
Last Modified: | 06 Jan 2025 09:49 |
URI: | https://orca.cardiff.ac.uk/id/eprint/173299 |
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