Iron catalyzed dehydrocoupling of amine- and phosphine-boranes

Coles, Nathan T. ORCID: https://orcid.org/0000-0001-6190-9080 and Webster, Ruth L. 2017. Iron catalyzed dehydrocoupling of amine- and phosphine-boranes. Israel Journal of Chemistry 57 (12) , pp. 1070-1081. 10.1002/ijch.201700018

Full text not available from this repository.

Abstract

Catalytic dehydrocoupling methodologies, whereby dihydrogen is released from a substrate (or intermolecularly from two substrates) is a mild and efficient method to construct main group element-main group element bonds, the products of which can be used in advanced materials, and also for the development of hydrogen storage materials. With growing interest in the potential of compounds such as ammonia-borane to act as hydrogen storage materials which contain a high weight\% of H2, along with the current heightened interest in base metal catalyzed processes, this review covers recent developments in amine and phosphine dehydrocoupling catalyzed by iron complexes. The complexes employed, products formed and mechanistic proposals will be discussed.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	0021-2148
Date of Acceptance:	7 July 2017
Last Modified:	13 Nov 2024 16:45
URI:	https://orca.cardiff.ac.uk/id/eprint/173575

Actions (repository staff only)

Edit Item