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Identification of major component of male-produced aggregation pheromone of larger grain borer, Prostephanus truncatus (Horn) (Coleoptera: Bostrichidae)

Cork, A., Hall, D., Hodges, R. and Pickett, J. ORCID: https://orcid.org/0000-0002-8386-3770 1991. Identification of major component of male-produced aggregation pheromone of larger grain borer, Prostephanus truncatus (Horn) (Coleoptera: Bostrichidae). Journal of Chemical Ecology 17 (4) , pp. 789-803. 10.1007/BF00994201

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Abstract

Male beetles of the larger grain borer,Prostephanus truncatus Horn (Coleoptera: Bostrichidae) were shown to produce material causing an electroantennographic (EAG) response from both male and female beetles. Volatiles from mixed sex cultures were collected on Porapak Q and fractionated by liquid chromatography (LC) with gradient elution. The total volatiles and the fractions were analyzed by gas chromatography (GC) linked to EAG, and two compounds eluting in the same LC fraction elicited EAG responses from male and female beetles. These were assumed to be components of the male-produced aggregation pheromone. Amounts of these compounds obtained were very low and less than 10−3 times the amounts of the aggregation pheromone components produced by the related species,Rhyzopertha dominica, under similar conditions. The most abundant of these EAG-active compounds was identified as 1-methyiethyl (2E)-2-methyl-2-pentenoate by comparison of its GC retention times and mass spectrum with those of synthetic analogs. The synthetic compound elicited electrophysiological and behavioral responses in both male and female beetles significantly greater than those to structural analogs. This compound is attractive toP. truncatus beetles in the field, and has been given the trivial name of “trunc-call 1”.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Schools > Chemistry
Publisher: Springer
ISSN: 0098-0331
Date of Acceptance: 26 December 1990
Last Modified: 06 Feb 2026 15:30
URI: https://orca.cardiff.ac.uk/id/eprint/184491

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