Heterogeneously catalysed oxidation reactions with P450-like characteristics; radical reactions and the "elusive" oxygen state

Roberts, Meirion Wyn 2011. Heterogeneously catalysed oxidation reactions with P450-like characteristics; radical reactions and the "elusive" oxygen state. Catalysis Letters 141 (3) , pp. 365-369. 10.1007/s10562-010-0474-1

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Abstract

We consider how transient oxygen states, which provide low energy pathways in catalytic oxidation reaction at metal surfaces involving radical chemistry, can offer a view on the mechanism and why there is a lack of experimental evidence for the active oxygen state in the P450 enzyme system.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Biocatalysis – P450 – Oxygen transients – Radical reactions – Oxidation – Ammonia – Water – Silver – Zinc – Copper
Publisher:	Springer
ISSN:	1011-372X
Last Modified:	21 Oct 2016 02:21
URI:	https://orca.cardiff.ac.uk/id/eprint/18984

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