Anion recognition by highly sterically encumbered 1,2-diborylferrocenes

Morgan, Ian Rhys ORCID: https://orcid.org/0000-0002-0253-1855, Broomsgrove, Alexander E. J., Fitzpatrick, Philip, Vidovic, Dragoslav, Thompson, Amber L., Fallis, Ian Andrew ORCID: https://orcid.org/0000-0001-7361-0182 and Aldridge, Simon 2010. Anion recognition by highly sterically encumbered 1,2-diborylferrocenes. Organometallics 29 (21) , pp. 4762-4765. 10.1021/om1005337

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Abstract

The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)2 is found to be highly selective for CN−, with the uptake of F− being shown to be not only thermodynamically less favorable but also kinetically much slower

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	19 Oct 2022 09:10
URI:	https://orca.cardiff.ac.uk/id/eprint/20189

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