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Anion recognition by highly sterically encumbered 1,2-diborylferrocenes

Morgan, Ian Rhys ORCID:, Broomsgrove, Alexander E. J., Fitzpatrick, Philip, Vidovic, Dragoslav, Thompson, Amber L., Fallis, Ian Andrew ORCID: and Aldridge, Simon 2010. Anion recognition by highly sterically encumbered 1,2-diborylferrocenes. Organometallics 29 (21) , pp. 4762-4765. 10.1021/om1005337

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The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)2 is found to be highly selective for CN−, with the uptake of F− being shown to be not only thermodynamically less favorable but also kinetically much slower

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 0276-7333
Last Modified: 19 Oct 2022 09:10

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