Heteroaromatic analogues of dibenzylideneacetone (dba) and Pd02(het-dba)3complexes: effect of a thienyl moiety on the reactivity of Pd0(eta2-thn-dba)(PPh3)2/Pd0(PPh3)2(n= 1 or 2) and Pd0(eta2-th2-dba)(dppe)/Pd0(dppe) in oxidative addition reactions with iodobenzene

Sehnal, Petr, Taghzouti, Hanaa, Fairlamb, Ian J. S., Jutand, Anny, Lee, Adam Fraser and Whitwood, Adrian C. 2009. Heteroaromatic analogues of dibenzylideneacetone (dba) and Pd02(het-dba)3complexes: effect of a thienyl moiety on the reactivity of Pd0(eta2-thn-dba)(PPh3)2/Pd0(PPh3)2(n= 1 or 2) and Pd0(eta2-th2-dba)(dppe)/Pd0(dppe) in oxidative addition reactions with iodobenzene. Organometallics 28 (3) , pp. 824-829. 10.1021/om800975w

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Abstract

Palladium(0) complexes containing thienyl analogues of dibenzylidene acetone (dba) have been synthesized and characterized. Their reactivity toward PPh3 and dppe, to generate Pd0(η2-alkene)(PPh3)2 and Pd0(η2-alkene)(dppe) complexes, and their subsequent oxidative addition reactions with PhI, have been investigated.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	19 Mar 2016 22:41
URI:	https://orca.cardiff.ac.uk/id/eprint/23841

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