The reactivity of metallated nitrenium ions studied by FT-ICR

Yurkovich, Michael J., Duan, Penggao, Shea, Ryan C., Watkins, Michael A., Mandell, Sarah M., Tippmann, Eric Michael, Li, Sen Jason, Platz, Matthew S. and Kenttämaa, Hilkka I. 2009. The reactivity of metallated nitrenium ions studied by FT-ICR. International Journal of Mass Spectrometry 287 (1-3) , pp. 16-20. 10.1016/j.ijms.2009.03.011

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Abstract

The reactivity of two metallatednitrenium ions toward various substrates was examined in the gas phase. The nitrenium ions were generated by a reaction of benzoyl azide with laser-ablated Mg+ or Cu+ in a Fourier transform ion cyclotron resonance mass spectrometer. The two nitrenium ions show drastically different reactivity. While the Mg-nitrenium ion reacts by radical mechanisms (e.g., H atom abstraction), the Cu-nitrenium ion follows non-radical pathways (e.g., metal ion transfer).

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Nitrenium ion; Ion-molecule reaction; Magnesium cation; Copper cation; FT-ICR
Publisher:	Elsevier
ISSN:	1387-3806
Last Modified:	19 Mar 2016 22:41
URI:	https://orca.cardiff.ac.uk/id/eprint/24321

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