Weller, Michael D., Kariuki, Benson ![]() |
Official URL: http://dx.doi.org/10.1016/j.tetlet.2008.05.081
Abstract
A stereoselective haloclestannylation of (E)-beta-stannylvinyisilane 6 has been used to access a range of (E)-beta-halovinylsilanes. Most notably, the beta-fluorovinylsilane 14 was accessed in high yield using the Select-fluor (R) reagent, and subsequently converted into a masked hexayne 22. Release of the hexayne 25 was achieved by exposing 22 to sub-stoichiometric quantities of fluoride.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | Vinylsilanes; Oligoynes; Polyynes; β-Elimination; Tin–halogen exchange |
Publisher: | Elsevier |
ISSN: | 0040-4039 |
Last Modified: | 19 Oct 2022 10:38 |
URI: | https://orca.cardiff.ac.uk/id/eprint/25060 |
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