Hossain, G. M. Golzar and Amoroso, Angelo James ![]() |
Abstract
In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal-prismatic geometry arising from the two sulfadiazinate ligands and one 4,4'-dimethyl-2,2'-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl-formamide mol-ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetra-hedral. The crystal structure involves N-H⋯O hydrogen bonds which link mol-ecules into a three-dimensional network. Weak C-H⋯O hydrogen bonds are also observed.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | International Union of Crystallography |
ISSN: | 1600-5368 |
Last Modified: | 20 Oct 2022 07:40 |
URI: | https://orca.cardiff.ac.uk/id/eprint/26038 |
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