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Bis[4-amino-N-(pyrimidin-2-yl-kappaN)benzenesulfonamidato-kappaN](4,4'-dimethyl-2,2'-bipyridine-kappa2N,N')cadmium dimethylformamide disolvate

Hossain, G. M. Golzar and Amoroso, Angelo James ORCID: 2012. Bis[4-amino-N-(pyrimidin-2-yl-kappaN)benzenesulfonamidato-kappaN](4,4'-dimethyl-2,2'-bipyridine-kappa2N,N')cadmium dimethylformamide disolvate. Acta Crystallographica Section E Structure Reports Online 68 (3) , m276-m277. 10.1107/S1600536812004412

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In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal-prismatic geometry arising from the two sulfadiazinate ligands and one 4,4'-dimethyl-2,2'-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl-formamide mol-ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetra-hedral. The crystal structure involves N-H⋯O hydrogen bonds which link mol-ecules into a three-dimensional network. Weak C-H⋯O hydrogen bonds are also observed.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: International Union of Crystallography
ISSN: 1600-5368
Last Modified: 20 Oct 2022 07:40

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