Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity

Newman, Paul David ORCID: https://orcid.org/0000-0002-1808-1211, Cavell, Kingsley John and Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897 2012. Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity. Chemical Communications 48 (52) , pp. 6511-6513. 10.1039/c2cc33036a

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Abstract

An unusual example of diastereoselectivity has been observed in Cu(κ3-P,C,P′-1)X complexes where 1 is an asymmetric tridentate ligand containing a bicyclic NHC framework and X is a halide. When X is Cl−, the SCu isomer is formed selectively whereas when X = I− the RCu diastereomer is preferred.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of First Compliant Deposit:	30 March 2016
Last Modified:	06 May 2023 06:36
URI:	https://orca.cardiff.ac.uk/id/eprint/33753

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