Acylation of alkylidenepyrrolidines with heterocumulenes - a reinvestigation

Davies, Christopher D., Elliott, Mark Christopher ORCID: https://orcid.org/0000-0003-0132-0818 and Wood, John L. 2006. Acylation of alkylidenepyrrolidines with heterocumulenes - a reinvestigation. Tetrahedron 62 (48) , pp. 11158-11164. 10.1016/j.tet.2006.09.014

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Abstract

The reactions of alkylidenepyrrolidine esters with isocyanates generally favour C-acylation, except in the case of benzyl isocyanate. Reactions with alkyl isocyanates are slow, and require forcing conditions. Reactions with isothiocyanates give exclusively the C-acylated products.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0040-4020
Last Modified:	21 Oct 2022 10:20
URI:	https://orca.cardiff.ac.uk/id/eprint/39872

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