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Acylation of alkylidenepyrrolidines with heterocumulenes - a reinvestigation

Davies, Christopher D., Elliott, Mark Christopher and Wood, John L. 2006. Acylation of alkylidenepyrrolidines with heterocumulenes - a reinvestigation. Tetrahedron 62 (48) , pp. 11158-11164. 10.1016/j.tet.2006.09.014

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The reactions of alkylidenepyrrolidine esters with isocyanates generally favour C-acylation, except in the case of benzyl isocyanate. Reactions with alkyl isocyanates are slow, and require forcing conditions. Reactions with isothiocyanates give exclusively the C-acylated products.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Elsevier
ISSN: 0040-4020
Last Modified: 04 Jun 2017 04:29

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