Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2− and Yb(III) units

Miller, Thomas A., Jeffery, John C., Ward, Michael D., Adams, Harry, Pope, Simon J. A. ORCID: https://orcid.org/0000-0001-9110-9711 and Faulkner, Stephen 2004. Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2− and Yb(III) units. Dalton Transactions 2004 (10) , pp. 1524-1526. 10.1039/b404820b

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Abstract

Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)4]2− with Yb(III) provides coordination polymers or oligomers containing Ru–CN–Yb bridges; in [K(H2O)4][Yb(H2O)6][Ru(bipy)(CN)4]2·5H2O Ru → Yb energy-transfer (k > 5 × 106 s−1) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC
ISSN:	1477-9226
Last Modified:	21 Oct 2022 10:53
URI:	https://orca.cardiff.ac.uk/id/eprint/41642

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