A spirobifluorene-based polymer of intrinsic microporosity with improved performance for gas separation

Bezzu, Caterina Grazia, Carta, Mariolino ORCID: https://orcid.org/0000-0003-0718-6971, Tonkins, Alexander, Jansen, Johannes C., Bernardo, Paola, Bazzarelli, Fabio and McKeown, Neil B. 2012. A spirobifluorene-based polymer of intrinsic microporosity with improved performance for gas separation. Advanced Materials 24 (44) , pp. 5930-5933. 10.1002/adma.201202393

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Abstract

A highly gas-permeable polymer with enhanced selectivities is prepared using spirobifluorene as the main structural unit. The greater rigidity of this polymer of intrinsic microporosity (PIM-SBF) facilitates gas permeability data that lie above the 2008 Robeson upper bound, which is the universal performance indicator for polymer gas separation membranes.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	polymer membranes; gas separation; spirobifluorene; intrinsic microporosity
Publisher:	Wiley Blackwell
ISSN:	0935-9648
Funders:	EU, EPSRC
Last Modified:	24 Oct 2022 09:59
URI:	https://orca.cardiff.ac.uk/id/eprint/42811

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