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Aryl azide photochemistry in defined protein environments

Morris, Josephine Lydia, Reddington, Samuel C., Murphy, Damien Martin ORCID:, Jones, Darran Dafydd ORCID:, Platts, James Alexis ORCID: and Tippmann, Eric Michael 2013. Aryl azide photochemistry in defined protein environments. Organic Letters 15 (4) , pp. 728-731. 10.1021/ol3028779

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A genetically encoded precursor to an aryl nitrene, para-azidophenylalanine, was introduced site specifically into proteins to deduce if distinct environments were capable of caging a reactive organic intermediate. Following photolysis of mutant T4 lysozyme or green fluorescent proteins, EPR spectra showed, respectively, the presence of a triplet nitrene and an anilino radical.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Biosciences
Subjects: Q Science > QD Chemistry
Publisher: ACS
ISSN: 1523-7060
Funders: EPSRC
Last Modified: 24 Oct 2022 10:42

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