Simplifying iron-phosphine catalysts for cross-coupling reactions

Bedford, R. B., Carter, Emma ORCID: https://orcid.org/0000-0001-6691-2377, Cogswell, P. M., Gower, N. J., Haddow, M. F., Harvey, J. N., Murphy, Damien Martin ORCID: https://orcid.org/0000-0002-5941-4879, Neeve, E. C. and Nunn, J. 2013. Simplifying iron-phosphine catalysts for cross-coupling reactions. Angewandte Chemie - International Edition 52 (4) , pp. 1285-1288. 10.1002/anie.201207868

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Abstract

Any old iron? Iron catalysts based on the widely available diphosphine ligand bis(diphenylphosphino)ethane have not previously fared particularly well in iron-catalyzed cross-coupling processes. However, this turns out not to be due to any inherently poor performance associated with the ligand, but rather the need to form a bis-chelate complex, either before or during the formation of an active FeI species.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	alkyl halides; catalysis; cross-coupling; iron; phosphine ligands
Publisher:	Wiley-Blackwell
ISSN:	1521-3773
Funders:	EPSRC
Last Modified:	16 Oct 2024 10:18
URI:	https://orca.cardiff.ac.uk/id/eprint/46629

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