Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction

Bonnet, Ludovic G., Douthwaite, Richard E. and Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897 2003. Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction. Organometallics 22 (21) , pp. 4187-4189. 10.1021/om034050z

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Abstract

Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)−imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	24 Oct 2022 11:10
URI:	https://orca.cardiff.ac.uk/id/eprint/47203

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