The first spirobifluorenes containing two binaphthyl moieties

Russell, A. G., Spencer, N. S., Philp, D., Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897 and Snaith, J. S. 2003. The first spirobifluorenes containing two binaphthyl moieties. Organometallics 22 (26) , pp. 5589-5592. 10.1021/om030422s

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Abstract

The first spirobifluorenes comprising two binaphthyl moieties with silicon or germanium at the site of fusion have been synthesized and fully characterized. X-ray crystallographic analysis reveals that both molecules have highly distorted structures, resulting in a low barrier for interconversion between the two atropisomers; the barrier was calculated from the temperature dependency of the NMR spectra

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	24 Oct 2022 11:11
URI:	https://orca.cardiff.ac.uk/id/eprint/47208

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