Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions

Pascu, M., Clarkson, G. J., Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897 and Hannon, M. J. 2006. Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions. Dalton Transactions (22) , pp. 2635-2642. 10.1039/B517643C

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Abstract

The design of supramolecular architectures based on isoquinoline-imine ligand systems is described. The isoquinoline affords an extended π surface and the use of this surface to obtain self-recognition and consequent π–π aggregation is investigated. The approach is effective in that each of four complexes is observed to aggregate through these interactions. Other π–π interactions can interfere with the aggregation indicating that a larger π-surface may be required to obtain complete control over the aggregation of the units.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC
ISSN:	1477-9226
Last Modified:	24 Oct 2022 11:11
URI:	https://orca.cardiff.ac.uk/id/eprint/47231

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