A near-infrared electrochromic window based on an Sb-doped SnO2 electrode modified with a Ru-dioxolene complex

Garcia Canadas, Jorge, Meacham, A. P., Peter, L. M. and Ward, M. D. 2003. A near-infrared electrochromic window based on an Sb-doped SnO2 electrode modified with a Ru-dioxolene complex. Angewandte Chemie - International Edition 42 (26) , pp. 3011-3014. 10.1002/anie.200351338

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Abstract

A window of opportunity: The ligand-centred redox activity of complex 1 (depicted) is exploited to make an electrochromic window, which demonstrates rapid and reversible changes in optical transmission at 940 nm. The window is made by adsorbing 1 onto a nanocrystalline Sb-doped SnO2 film attached to a transparent conducting substrate and cycling the applied potential through the catecholate/semiquinone redox couple.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Engineering
Subjects:	Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General)
Uncontrolled Keywords:	cyclic voltammetry; electrochemistry; electrochromism; near infrared; ruthenium
Publisher:	Wiley-Blackwell
ISSN:	1521-3773
Last Modified:	19 Mar 2016 23:21
URI:	https://orca.cardiff.ac.uk/id/eprint/48399

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