An ENDOR study of oxomolybdenum(V) tris(pyrazolyl)borate complexes; identification of couplings to boron and other

Farley, Robert D., Hoefer, Peter, Maher, John P., McCleverty, JA, Murphy, Damien Martin ORCID: https://orcid.org/0000-0002-5941-4879, Rowlands, Christopher C., Ung, Van A. and Ward, Michael D. 2002. An ENDOR study of oxomolybdenum(V) tris(pyrazolyl)borate complexes; identification of couplings to boron and other. Magnetic Resonance in Chemistry 40 (11) , pp. 683-686. 10.1002/mrc.1090

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Abstract

11B hyperfine and quadrupolar couplings have been observed by the electron magnetic resonance techniques electron nuclear double resonance and hyperfine sublevel correlation spectroscopy for some tris(pyrazolyl)borato-oxomolybdenum(V) and related nitrosyl complexes including a dinuclear B–B linked complex. The spectra are interpreted according to the electron delocalization onto the ligands, especially the pyrazolylborate.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Wiley-Blackwell
ISSN:	0749-1581
Last Modified:	24 Oct 2022 11:32
URI:	https://orca.cardiff.ac.uk/id/eprint/48503

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