Tribenzotriquinacene-based polymers of intrinsic microporosity

Vile, James, Carta, Mariolino ORCID: https://orcid.org/0000-0003-0718-6971, Bezzu, Caterina Grazia and McKeown, Neil B. 2011. Tribenzotriquinacene-based polymers of intrinsic microporosity. Polymer Chemistry 2 (10) , pp. 2257-2260. 10.1039/c1py00294e

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Abstract

Bowl-shaped tribenzotriquinacene (TBTQ) derivatives containing hydroxyl groups at their peripheral sites are successful monomers for the synthesis of polymers of intrinsic microporosity (PIMs) with examples of both network and non-network PIMs demonstrated. Nitrogen adsorption measurements reveal apparent surface areas in the range of 560–670 m2 g−1 for the TBTQ-PIMs. A network structure and i-propyl, rather than methyl substitution at the apical site of the TBTQ unit, appear to favour porosity.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1759-9954
Funders:	EPSRC
Last Modified:	11 Dec 2022 08:47
URI:	https://orca.cardiff.ac.uk/id/eprint/49463

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