Vile, James, Carta, Mariolino ORCID: https://orcid.org/0000-0003-0718-6971, Bezzu, Caterina Grazia and McKeown, Neil B. 2011. Tribenzotriquinacene-based polymers of intrinsic microporosity. Polymer Chemistry 2 (10) , pp. 2257-2260. 10.1039/c1py00294e |
Official URL: http://dx.doi.org/10.1039/c1py00294e
Abstract
Bowl-shaped tribenzotriquinacene (TBTQ) derivatives containing hydroxyl groups at their peripheral sites are successful monomers for the synthesis of polymers of intrinsic microporosity (PIMs) with examples of both network and non-network PIMs demonstrated. Nitrogen adsorption measurements reveal apparent surface areas in the range of 560–670 m2 g−1 for the TBTQ-PIMs. A network structure and i-propyl, rather than methyl substitution at the apical site of the TBTQ unit, appear to favour porosity.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 1759-9954 |
Funders: | EPSRC |
Last Modified: | 11 Dec 2022 08:47 |
URI: | https://orca.cardiff.ac.uk/id/eprint/49463 |
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