cis-Dichloridotetrakis(dimethyl sulfoxide-[kappa]O)chromium(III) chloride dimethyl sulfoxide monosolvate

Al-Najjar, Nada A., Al-Sudani, Abdul-Razak, Shanshal, Muthana A., Mousa, Falih H. and Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897 2013. cis-Dichloridotetrakis(dimethyl sulfoxide-[kappa]O)chromium(III) chloride dimethyl sulfoxide monosolvate. Acta Crystallographica Section E - Structure Reports Online 69 (7) , m395. 10.1107/S160053681301622X

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Abstract

The structure of the title compound, [CrCl2(C2H6OS)4]Cl·C2H6OS, consists of a CrIII ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl2O4 octahedron. An isolated Cl- counter-anion and a positionally disordered DMSO molecule [occupancy ratio 0.654 (4):0.346 (4)] are also present. In the structure, the complex cations interact with the Cl- counter-anions and the DMSO solvent molecules via weak C-H...Cl and C-H...O interactions, forming a three-dimensional network.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	International Union of Crystallography
ISSN:	1600-5368
Last Modified:	24 Oct 2022 11:58
URI:	https://orca.cardiff.ac.uk/id/eprint/49914

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