Altermann, Sabine
2008.
Novel chiral hypervalent iodoarenes in enantioselective iodocatalysis and oxidation reactions.
PhD Thesis,
Cardiff University.
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Abstract
A range of enantiomerically pure iodine compounds has been synthesised and either oxidised to the corresponding hypervalent iodine compound and used as oxidant or employed as catalysts in a range of reactions together with different oxidants in stoichiometric amounts in order to form the respective hypervalent iodine species in situ. Three different enantioselective catalytic reactions have been investigated: cc-acetoxylation of ketones, halolactonisation of pentenoic acids and oc-oxytosylation of ketones. Also - probably for the first time - alkyliodides have been employed as catalysts in these transformations.
Item Type: | Thesis (PhD) |
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Status: | Unpublished |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
ISBN: | 9781303213823 |
Date of First Compliant Deposit: | 30 March 2016 |
Last Modified: | 04 Nov 2024 11:15 |
URI: | https://orca.cardiff.ac.uk/id/eprint/54769 |
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