Novel chiral hypervalent iodoarenes in enantioselective iodocatalysis and oxidation reactions

Altermann, Sabine 2008. Novel chiral hypervalent iodoarenes in enantioselective iodocatalysis and oxidation reactions. PhD Thesis, Cardiff University.

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Abstract

A range of enantiomerically pure iodine compounds has been synthesised and either oxidised to the corresponding hypervalent iodine compound and used as oxidant or employed as catalysts in a range of reactions together with different oxidants in stoichiometric amounts in order to form the respective hypervalent iodine species in situ. Three different enantioselective catalytic reactions have been investigated: cc-acetoxylation of ketones, halolactonisation of pentenoic acids and oc-oxytosylation of ketones. Also - probably for the first time - alkyliodides have been employed as catalysts in these transformations.

Item Type:	Thesis (PhD)
Status:	Unpublished
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
ISBN:	9781303213823
Date of First Compliant Deposit:	30 March 2016
Last Modified:	04 Nov 2024 11:15
URI:	https://orca.cardiff.ac.uk/id/eprint/54769

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