Mania, Philipp, Verel, Rene, Jenny, Florian, Hammond, Ceri ![]() |
Official URL: http://dx.doi.org/10.1002/chem.201300842
Abstract
Anchoring titanium: Grafting of TiCl4 to site-isolated silanol groups on silica initially leads to freely rotating species. Upon heating, a thermal restructuring takes place, causing the elimination of TiCl4 and the formation of more strongly anchored titanium species, which were found to be highly active and stable epoxidation catalysts.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | heterogeneous catalysis; epoxidation; NMR spectroscopy; structure–activity relationships; titanium |
Publisher: | Wiley Blackwell |
ISSN: | 0947-6539 |
Last Modified: | 25 Oct 2022 09:10 |
URI: | https://orca.cardiff.ac.uk/id/eprint/57523 |
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