Efficient catalysts for telomerization of butadiene with amines

Grotevendt, A., Bartolome, M., Nielsen, D. J., Spannenberg, A., Jackstell, R., Cavell, Kingsley John, Oro, L. A. and Beller, M. 2007. Efficient catalysts for telomerization of butadiene with amines. Tetrahedron Letters 48 (52) , pp. 9203-9207. 10.1016/j.tetlet.2007.10.076

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Abstract

In situ-generated N-heterocyclic carbene (NHC) palladium catalysts and isolated NHC-palladium complexes have been tested for the telomerization reaction of 1,3-butadiene with primary and secondary amines. Superior catalyst activity (TON up to 400.000) and selectivity are obtained. Applying optimized conditions a variety of octa-2,7-dienylamines were prepared in high yield and excellent selectivity.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Amines; 1,3-Butadiene; Carbene; Homogeneous catalysis; Palladium
Publisher:	Elsevier
ISSN:	0040-4039
Last Modified:	19 Mar 2016 22:09
URI:	https://orca.cardiff.ac.uk/id/eprint/5966

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