Msayib, Kadhum, Book, David, Budd, Peter M., Chaukura, Nhamo, Harris, Kenneth David Maclean  ORCID: https://orcid.org/0000-0001-7855-8598, Helliwell, Madeleine, Tedds, Steven, Walton, Allan, Warren, John E., Xu, Mingcan and McKeown, Neil B.
2009.
Nitrogen and hydrogen adsorption by an organic microporous crystal.
Angewandte Chemie. International Edition
48
(18)
, pp. 3273-3277.
10.1002/anie.200900234
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Official URL: http://dx.doi.org/10.1002/anie.200900234
Abstract
Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3′,4,4′-tetra(trimethylsilylethynyl)biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Uncontrolled Keywords: | adsorption; hydrogen storage; interconnectivity; microporous materials; organic zeolites |
| Publisher: | Wiley-Blackwell |
| ISSN: | 1433-7851 |
| Funders: | EPSRC |
| Date of First Compliant Deposit: | 30 March 2016 |
| Last Modified: | 02 Oct 2025 20:15 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/6072 |
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