Msayib, Kadhum, Book, David, Budd, Peter M., Chaukura, Nhamo, Harris, Kenneth David Maclean ![]() |
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Official URL: http://dx.doi.org/10.1002/anie.200900234
Abstract
Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3′,4,4′-tetra(trimethylsilylethynyl)biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | adsorption; hydrogen storage; interconnectivity; microporous materials; organic zeolites |
Publisher: | Wiley-Blackwell |
ISSN: | 1433-7851 |
Funders: | EPSRC |
Date of First Compliant Deposit: | 30 March 2016 |
Last Modified: | 06 May 2023 18:48 |
URI: | https://orca.cardiff.ac.uk/id/eprint/6072 |
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