Thiocyanate complexes of uranium in multiple oxidation states: a combined structural, magnetic, spectroscopic, spectroelectrochemical and theoretical study

Hashem, Emtithal, Platts, James Alexis ORCID: https://orcid.org/0000-0002-1008-6595, Hartl, František, Lorusso, Giulia, Evangelisti, Marco, Schulzke, Carola and Baker, Robert J. 2014. Thiocyanate complexes of uranium in multiple oxidation states: a combined structural, magnetic, spectroscopic, spectroelectrochemical and theoretical study. Inorganic Chemistry 53 (16) , pp. 8624-8637. 10.1021/ic501236j

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Abstract

Uranium thiocyanate complexes in different oxidation states have been studied by SQUID magnetometry, photoluminescence spectroscopy, and spectroelectrochemistry. The magnetic properties of [U(NCS)8]4− have been studied with respect to the geometry around the uranium ion. The thiocyanate ligands in this complex have been found to undergo unusual anodic reactivity.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry Professional Services > Advanced Research Computing @ Cardiff (ARCCA)
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Uranium; magnetic properties; photoluminescence; DFT.
Publisher:	American Chemical Society
ISSN:	0020-1669
Date of Acceptance:	29 July 2014
Last Modified:	27 Oct 2022 08:30
URI:	https://orca.cardiff.ac.uk/id/eprint/62517

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