Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831, Simmonds, Hayley R., Wadepohl, Hubert, Wood, Paul T., Gade, Lutz H. and Wright, Dominic S. 2014. Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimide. Australian Journal of Chemistry 67 (7) , pp. 1030-1036. 10.1071/CH14170 |
Official URL: http://dx.doi.org/10.1071/CH14170
Abstract
During an investigation of the synthesis of the new mono- and bis(guanidinate) complexes [{iPr2NC(···NiPr)2}GaCl2] (2) and [{iPr2NC(···NiPr)2}2GaCl] (3) from the in situ reactions of the lithium guanidinate [{iPr2NC(···NiPr)2}Li]n (1) with GaCl3, an unexpected new guanidinate expansion reaction was uncovered in which it is found that the nucleophilic addition of 2 to the carbodiimide, iPrN=C=NiPr, gives [iPrN{C(NiPr)=NiPr}{C(=NiPr)NiPr2}GaCl2] (4), containing an unusual bis(diguanidinate) ligand.
Item Type: | Article |
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Date Type: | Published Online |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | CSIRO Publishing |
ISSN: | 0004-9425 |
Date of Acceptance: | 28 April 2014 |
Last Modified: | 27 Oct 2022 09:16 |
URI: | https://orca.cardiff.ac.uk/id/eprint/65036 |
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