Physical mixing of metal acetates: optimisation of catalyst parameters to produce highly active bimetallic catalysts

Miedziak, Peter, Kondrat, Simon A., Sajjad, Noreen, King, Gavin Morgan, Douthwaite, Mark, Shaw, Greg, Brett, Gemma Louise, Edwards, Jennifer ORCID: https://orcid.org/0000-0003-4089-2827, Morgan, David John ORCID: https://orcid.org/0000-0002-6571-5731, Hussain, Ghulam and Hutchings, Graham John ORCID: https://orcid.org/0000-0001-8885-1560 2013. Physical mixing of metal acetates: optimisation of catalyst parameters to produce highly active bimetallic catalysts. Catalysis Science & Technology 3 (11) , pp. 2910-2917. 10.1039/c3cy00263b

Full text not available from this repository.

Abstract

We have investigated the optimisation of the catalytic parameters for the preparation of catalysts by the simple mixing and thermal treatment of a support and metal acetate precursors. We have studied the effect of metal ratio and metal loading to produce a catalyst which has the optimum activity for a variety of reactions including benzyl alcohol oxidation, glycerol oxidation and the direct synthesis of hydrogen peroxide. We have demonstrated the high activity of these catalyst's for a variety of substrates and performed XPS and XRD studies on the catalysts to help elucidate the origin of the catalysts improved activity.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Research Institutes & Centres > Cardiff Catalysis Institute (CCI) Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	2044-4753
Date of Acceptance:	7 May 2013
Last Modified:	14 Nov 2022 07:48
URI:	https://orca.cardiff.ac.uk/id/eprint/66612

Citation Data

Cited 9 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item