Physical mixing of metal acetates: optimisation of catalyst parameters to produce highly active bimetallic catalysts

Miedziak, Peter, Kondrat, Simon A., Sajjad, Noreen, King, Gavin Morgan, Douthwaite, Mark, Shaw, Greg, Brett, Gemma Louise, Edwards, Jennifer ORCID: https://orcid.org/0000-0003-4089-2827, Morgan, David John ORCID: https://orcid.org/0000-0002-6571-5731, Hussain, Ghulam and Hutchings, Graham John ORCID: https://orcid.org/0000-0001-8885-1560 2013. Physical mixing of metal acetates: optimisation of catalyst parameters to produce highly active bimetallic catalysts. Catalysis Science & Technology 3 (11) , pp. 2910-2917. 10.1039/c3cy00263b

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Abstract

We have investigated the optimisation of the catalytic parameters for the preparation of catalysts by the simple mixing and thermal treatment of a support and metal acetate precursors. We have studied the effect of metal ratio and metal loading to produce a catalyst which has the optimum activity for a variety of reactions including benzyl alcohol oxidation, glycerol oxidation and the direct synthesis of hydrogen peroxide. We have demonstrated the high activity of these catalyst's for a variety of substrates and performed XPS and XRD studies on the catalysts to help elucidate the origin of the catalysts improved activity.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Cardiff Catalysis Institute (CCI) Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	2044-4753
Date of Acceptance:	7 May 2013
Last Modified:	14 Nov 2022 07:48
URI:	https://orca.cardiff.ac.uk/id/eprint/66612

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