Photoinduced energy transfer in a conformationally flexible Re(I)/Ru(II) dyad probed by time-resolved infrared spectroscopy: Effects of conformation and spatial localization of excited states

Easun, Timothy ORCID: https://orcid.org/0000-0002-0713-2642, Alsindi, Wassim Z., Towrie, Michael, Ronayne, Kate L., Sun, Xue-Zhong, Ward, Michael D. and George, Michael W. 2008. Photoinduced energy transfer in a conformationally flexible Re(I)/Ru(II) dyad probed by time-resolved infrared spectroscopy: Effects of conformation and spatial localization of excited states. Inorganic Chemistry 47 (12) , pp. 5071-5078. 10.1021/ic702005w

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Abstract

A combination of luminescence and picosecond- and nanosecond-time-scale time-resolved IR studies has been used to eludicate the photophysical behavior of the dyad RuLRe, in which a combination of (i) different conformations of the flexible bridging ligand and (ii) different 3MLCT states on the RuII acceptor leads to the presence of several different Re → Ru energy-transfer rates being identified.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0020-1669
Last Modified:	28 Oct 2022 08:30
URI:	https://orca.cardiff.ac.uk/id/eprint/71025

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