Isothiourea-mediated stereoselectiveC-acylation of silyl ketene acetals

Woods, Philip A., Morrill, Louis ORCID: https://orcid.org/0000-0002-6453-7531, Lebl, Tomas, Slawin, Alexandra M. Z., Bragg, Ryan A. and Smith, Andrew D. 2010. Isothiourea-mediated stereoselectiveC-acylation of silyl ketene acetals. Organic Letters 12 (11) , pp. 2660-2663. 10.1021/ol1008747

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Abstract

Isothiourea DHPB promotes the diastereoselective C-acylation of silyl ketene acetals with anhydrides or benzoyl fluoride, giving 3-acyl-3-aryl or 3-acyl-3-alkylfuranones in excellent yields and stereoselectivities (up to 99:1 dr).

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	ACS
ISSN:	1523-7060
Last Modified:	28 Oct 2022 09:22
URI:	https://orca.cardiff.ac.uk/id/eprint/74305

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