Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Pd-Ru/TiO2 catalyst - an active and selective catalyst for furfural hydrogenation

Aldosari, Dr Obaid, Iqbal, Sarwat, Miedziak, Peter John, Brett, Gemma Louise, Jones, Daniel R., Liu, Xi, Edwards, Jennifer Kelly ORCID: https://orcid.org/0000-0003-4089-2827, Morgan, David John ORCID: https://orcid.org/0000-0002-6571-5731, Knight, David William and Hutchings, Graham ORCID: https://orcid.org/0000-0001-8885-1560 2016. Pd-Ru/TiO2 catalyst - an active and selective catalyst for furfural hydrogenation. Catalysis Science & Technology 6 , pp. 234-242. 10.1039/C5CY01650A

[thumbnail of Aldosari et al 2015.pdf]
Preview
PDF - Published Version
Available under License Creative Commons Attribution.

Download (1MB) | Preview

Abstract

The selective hydrogenation of furfural at ambient temperature has been investigated using a Pd/TiO2 catalyst. The effect of the solvent was studied and high activity and selectivity to 2-methylfuran and furfuryl alcohol was observed using octane as solvent but a number of byproducts were observed. The addition of Ru to the PdTiO2 catalyst decreased the catalytic activity but improved the selectivity towards 2-methylfuran and furfuryl alcohol with decreased byproduct formation. Variation of the Ru/Pd ratio has shown an interesting effect on the selectivity. The addition of a small amount of Ru (1 wt. %) shifted the selectivity towards furfuryl alcohol and 2-methylrofuran. Further increasing the Ru ratio decreased the catalytic activity and also showed a very poor selectivity to 2-methylfuran.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 2044-4753
Funders: EPSRC
Date of First Compliant Deposit: 30 March 2016
Date of Acceptance: 30 October 2015
Last Modified: 16 May 2024 20:34
URI: https://orca.cardiff.ac.uk/id/eprint/80393

Citation Data

Cited 115 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics