Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study

O'Connor, Alice E, Mirzadeh, Nedaossadat, Bhargava, Suresh K, Easun, Timothy ORCID: https://orcid.org/0000-0002-0713-2642, Schroder, M. and Blake, Alexander J. 2016. Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications- Royal Society of Chemistry 52 , pp. 6769-6772. 10.1039/C6CC00923A

Preview

PDF - Published Version Available under License Creative Commons Attribution. Download (2MB) | Preview

Abstract

High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveals the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of First Compliant Deposit:	30 March 2016
Date of Acceptance:	11 March 2016
Last Modified:	05 May 2023 02:24
URI:	https://orca.cardiff.ac.uk/id/eprint/87890

Citation Data

Cited 12 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item